Exciton absorption spectra of thin films of RbCu2Cl3 and Rb2Cu3Cl5 ternary compounds
E. N. Kovalenko
Kharkiv National University of Radio Electronics, Kharkiv 61166, Ukraine
E-mail: olena.kovalenko@nure.ua
O. N. Yunakova and N. N. Yunakov
Kharkiv National University, Kharkiv 61022, Ukraine
E-mail: o.n.yunakova@gmail.com
nnyunakov@ukr.net
pos Анотація:660
Received February 15, 2021, published online March 26, 2021
Abstract
The absorption spectra of RbCu2Cl3 and Rb2Cu3Cl5 thin films w ere studied in the 2–6 eV spectral and 90–450 K temperature ranges. The localization of excitons in CuCl43- structural elements of crystal lattice of compounds,three-dimensional nature of excitons in RbCu2Cl3 and two-dimensional nature of excitons in Rb2Cu3Cl5 were established. The exciton spectra of RbCu2Cl3 and Rb2Cu3Cl5 thin films were interpreted based on the transitions in the Cu+ ion.
Key words: thin films, absorption spectra, excitons.
