Fizika Nizkikh Temperatur: Volume 47, Number 6 (June 2021), p. 547-569    ( to contents , go back )

Interatomic interaction within a 4He–4He dimer with mobile nuclei

K. A. Chishko

B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine Kharkiv 61103, Ukraine
pos Анотація:

Received January 22, 2021, published online April 26, 2021


Schrödinger equation for system of two mobile spinless nucleus with Z0 = 2 and four electrons (4He2-dimer) has been solved in the framework of exact diagonalization approach. The spectrum has been obtained with basis of 1134 functions built as direct product of one-particle hydrogen-like functions which are solutions of the exactly solved Sturm–Liouville problem. The asymptotic (Van der Waals) behavior of interaction between two 4He atoms in the limit R0 → ∞ has been analyzed and discussed. The contribution to the interaction energy from four electronic spins on the 4He–4He bond has been calculated the exact diagonalization procedure.

Key words: He–He interatomic interaction, relativistic corrections, spin-spin interaction.

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